Decreasing the surface area increase or decrease the rate of reaction

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    The decrease of the cathodic reaction rate caused a decrease of the surface pH, leading to a disruption of the Mg(OH) 2-film and exposing of underlying catalytically active sites. Consequentially, the HE rate increased. In the buffered electrolyte, anodic polarization altered the near-surface pH less compared to the unbuffered electrolyte.
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